I know they didn't have the technology to work hard metals, but armor can also be made of leather, wood, and the like.
yup - all of the above. there's LOTS of room for more contributions on this topic to represent more cultures, but have a look at these previous threads, all of which include at least some discussion on armour
thread in Wednesday AMA: Mesoamerica
What were characteristics of the Native American/First Nations fighting methods, and how did they develop? - just a mention
What was war like in the Pacific Northwest before European contact?
Did the Native Americans and South Africans utilize metal body armor?
thread in AMA: Alaska, from Prehistory to Present
Have there ever been any Eskimo/Inuit conquerors/emperors/kings? - just a mention
... and I'm pretty sure I've missed a couple so if anyone can remember others, pls reply with links - thx!