The U.S. DID, in fact, bomb Tokyo extensively, just not with an atomic weapon. The US air campaign completely obliterated the city. Incendiary bombs were especially destructive in Japan, where many buildings were constructed using wood. Between 80,000 and 130,000 civilians were killed - more people than in the atomic blasts in Hiroshima and Nagasaki combined. For more: http://www.history.com/this-day-in-history/firebombing-of-tokyo
hi! here are a few more on Tokyo & other alternative atomic bomb targets
Why were the atomic bombs dropped on cities instead of the emperor's palace in Tokyo?
Was there any thought given in 1945 of using the atomic bombs on a military target instead of a city? - already in /u/OldWorldGlory's post
What was the next city the USA planned on using an atomic bomb on after Hiroshima and Nagasaki?
more on Tokyo (non-atomic bombing)
You might be interested in some previous threads on Tokyo and atomic bomb targeting during World War II:
They did. It's a widely known fact that the US firebombed Tokyo. If you're referring to nuclear weapons, it's widely accepted that Hiroshima and Nagasaki were chosen to give the impression that if Japan did not surrender, Tokyo would be next.