A quick search hasn't turned up much on the topic. What were the political and economic processes? How did the people adapt on both sides? How did decades of Soviet-led ideology play out in the new political climate?
I realize these processes would be ongoing and would continue past our 20 year mark, but what can we discuss about those first years of reunification?
It's easiest to understand the reintegration process as West Germany (The Federal German Republic, or BRD), annexing East Germany, (the German Democratic Republic, or DDR), as this is what happened.
After the Berlin Wall opened in 1989 (which was due to one security guard not knowing what to do after the leader of East Germany botched a press conference), the East German state steadily weakened, especially as soviet support stopped. East and West Germany first signed a treaty supporting economic and social reunification (eliminate border checks, common market) which lead to a later treaty of reunification. Under the reunification treaty East Germany was dissolved, and all it's lands joined West Germany, and became subject to West German laws and treaties. There was now only the Federal Republic of Germany (which is the official name of the Germany we know today). All of this was also ratified by the WWII Allies in a treaty as well, the Final Settlement in Respect to Germany and the German People.
For the first few years there were a lot of administrative hurdles, such as establishing bureaucracies and everything else required to run society effectively. Even though many East German government institutions existed, they were replaced or transformed to mirror the West German institutions which were now required.
What's important to note about East Germany is that everyone in that country knew at least a bit about West Germany and western culture, they are linguistically the same and all but a few corners (the island of Ruegen) received West German radio and TV signals. While East Germans did experience some shock in the first few years, these countries had only been separate for about 40 years, which really isn't that long.
Much of the economic development of the eastern German (or "new") states has been paid for by a "solidarity tax" on the much richer western states, which has inspired a bit of political animosity. Even though there has been much economic development the Eastern German states are still much poorer on average, but the living costs are significantly lower. The new states also have a demographic problem, as many young people left in the last 20 years to get higher paying jobs in the west or larger eastern cities (Berlin, Leipzig), as a consequence many small towns look like they might die out.
In the early years, the main changes someone in East Germany would have noticed in the early years were:
For West Germans: