I believe since they were on the security council they have veto power. United Nations General Assembly Resolution 2758
They did have a veto, but they couldn't use it because it was a credentials question, not a parliamentary(wrong term?) one.
In other words, it's not like someone in the Security council said, "I propose that P.R. China be recognized as the Chinese delegation, all in favor?"
Instead, a different set of representatives appeared in New York and said, "we're the real Chinese representatives, those guys are impostors."