Qin was more effective from the middle Warring States onwards. They weren't always more effective.
That being said I would say the reasons are:
Qin's land was fertile. It wasn't (originally) as populous, but Qin took over the heartland of the Zhou when the Zhou moved east (the event that ushered in the Spring and Autumn period). The Wei river valley was fertile and not hemmed in all sides by hostile states but had places they could expand into. When they go campaigning on their Eastern borders, they don't have to worry about another state taking advantage and attacking from their west (something other states had to put up with all the time) because there was no state on their west. I also read (but for the life of me can't remember where I read it from, might have been Cambridge's History of China) that they also embarked on huge irrigation projects of dikes and canals to make their lands even better and efficiently transfer goods.
Legalist reforms. Throughout the Warring States period, all the major players tried to concentrate power in the hand of the state/ruler and take it away from the aristocrats that made up the charioteers of the Spring and Autumn period. The Qin, on advice of Shang Yang, did this most completely. They adapted a very regimented society of five/ten mutually-responsible households (if one commits a crime, all are punished). All middle-men and aristocratic standings were (in theory) abolished. There was (in theory) no hereditary titles except that of the King, and everything was to be done by officers on the state's payroll. Society was to be structured around nuclear families of farmer-soldiers. There was to be no large family groups, and the entire population was to be available for military service. This allowed the Qin to mobilize its resources for war more efficiently than any other state.
Fun fact. If you go read legalist writings by Lord Shang and especially Hanfeizi, it reads like a checklist of what Big Brother is like from Orwell's 1984. The difference is Orwell says this is bad for the people, while Hanfeizi says it's good for the state/ruler.
Qin's successful conquest/colonization of the Sichuan basin really tipped the scale towards their favour with the addition of the vast and incredibly fertile Sichuan basin into their realm for the state to exploit, population to expand into, and to farm.