This gets asked here fairly often. Not to discourage more answers, but you may want to start with these:
https://www.reddit.com/r/AskHistorians/comments/4i6yxy/is_there_evidence_of_ptsd_in_soldiers_during/
https://www.reddit.com/r/AskHistorians/comments/4bw9fd/ptsd_in_ancient_up_to_medieval_age/
https://www.reddit.com/r/AskHistorians/comments/1cpusf/is_there_evidence_of_ptsd_in_ancient_warrior/
https://www.reddit.com/r/AskHistorians/comments/tk3nl/did_ancient_peoples_suffer_from_posttraumatic/
https://www.reddit.com/r/AskHistorians/comments/1j6ssm/are_there_any_indications_of_combat_ptsd_in/