I'm not referring to a specific building material which may not have been available to the ancients, but more to structures using a more modern construction process or technique to allow a larger, more complex building.
Follow up questions: why would they have found difficulty in building it?
Edit: I'm referring to the FIRST structure built after the fall of the empire, apologies.
This subreddit isn't a huge fan of 'first/lasts" questions, so just in case this runs afoul of the guidelines, here's an alternative question:
Did post-Rome European construction technology immediately surpass that of the Western Roman Empire, and if not, when did it finally reach that point?